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Abstract Spectral line surveys of the Taurus Molecular Cloud-1 (TMC-1) have led to the detection of more than 100 new molecular species, making it the most prolific source of interstellar molecular discoveries. These wide-band, high-sensitivity line surveys have been enabled by advances in telescope and receiver technology, particularly at centimeter and millimeter wavelengths. In this work, we present a statistical analysis of the molecular inventory of TMC-1 as probed by the GOTHAM large program survey from 3.9 to 36.4 GHz. To fully unlock the potential of the ∼29 GHz spectral bandwidth, we developed an automated pipeline for data reduction and calibration. We applied a Bayesian approach with Markov Chain Monte Carlo fitting to the calibrated spectra and constrained column densities for 102 molecular species detected in TMC-1, including 75 main isotopic species, 20 carbon-13 substituted species, and seven deuterium-substituted species. This list of the detected gas-phase molecules is populated by unsaturated hydrocarbons, in stark contrast to the oxygen-rich organics found in sublimated ices around protostars. Of note, 10 individual aromatic molecules were identified in the GOTHAM observations, contributing 0.011% of the gas-phase carbon budget probed by detected molecules when including CO and 6% when excluding CO. This work provides a reference set of observed gas-phase molecular abundances for interstellar clouds, offering a new benchmark for astrochemical theoretical models. 

ABSTRACT The internal velocity structure within dense gaseous cores plays a crucial role in providing the initial conditions for star formation in molecular clouds. However, the kinematic properties of dense gas at core scales (∼0.01−0.1 pc) has not been extensively characterized because of instrument limitations until the unique capabilities of GBT-Argus became available. The ongoing GBT-Argus Large Program, Dynamics in Star-forming Cores (DiSCo) thus aims to investigate the origin and distribution of angular momentum of star-forming cores. DiSCo will survey all starless cores and Class 0 protostellar cores in the Perseus molecular complex down to ∼0.01 pc scales with <0.05 km s−1 velocity resolution using the dense gas tracer N2H+. Here, we present the first data sets from DiSCo towards the B1 and NGC 1333 regions in Perseus. Our results suggest that a dense core’s internal velocity structure has little correlation with other core-scale properties, indicating these gas motions may be originated externally from cloud-scale turbulence. These first data sets also reaffirm the ability of GBT-Argus for studying dense core velocity structure and provided an empirical basis for future studies that address the angular momentum problem with a statistically broad sample. 

ABSTRACT We present the first results of high-spectral resolution (0.023 km s−1) N2H+ observations of dense gas dynamics at core scales (∼0.01 pc) using the recently commissioned Argus instrument on the Green Bank Telescope (GBT). While the fitted linear velocity gradients across the cores measured in our targets nicely agree with the well-known power-law correlation between the specific angular momentum and core size, it is unclear if the observed gradients represent core-scale rotation. In addition, our Argus data reveal detailed and intriguing gas structures in position–velocity (PV) space for all five targets studied in this project, which could suggest that the velocity gradients previously observed in many dense cores actually originate from large-scale turbulence or convergent flow compression instead of rigid-body rotation. We also note that there are targets in this study with their star-forming discs nearly perpendicular to the local velocity gradients, which, assuming the velocity gradient represents the direction of rotation, is opposite to what is described by the classical theory of star formation. This provides important insight on the transport of angular momentum within star-forming cores, which is a critical topic on studying protostellar disc formation.